PPT Slide
Weight fraction diluent (D)
xD = MassD / (M + MassD) where M = Mass original sample
Weight fraction phase J in diluted sample
xJ M / (M + MassD ) = xJ (1 - xD ) see Zevin, p130 for derivation
Mass absorption coefficient of diluted sample
(m )D* = mD* xD + (1 - xD) m * rule of additivity
We can now use ...(1) to make three equations in three unknowns (m * , Ki,J and xJ ):
(ii) (Ii,J )0 = Ki,J / m J * ie when xJ = 1, ie pure phase J
(iii) (Ii,J )D = Ki,J xJ(1-xD) / [m D*xD + (1 - xD) m * ]