Analysis of the environment of beryllium, magnesium and alkaline earth atoms in oxygen-containing compounds
V. A. Blatov,* L. V. Pogildyakova and V. N. Serezhkin
Samara State University, Ac. Pavlov Street 1, 443011 Samara, Russia. E-mail: blatov@ssu.samara.ru
(Received 25 March 1998; accepted 13 August 1998)
Abstract
About 2100 inorganic and organometallic compounds containing beryllium, magnesium and alkaline earth atoms (M) were investigated with Voronoi-Dirichlet polyhedra (VDPs). It is shown that the coordination numbers (CNs) of the M atoms in M0„ coordination polyhedra can be determined by means of VDPs without crystal-chemical radii. The distributions of the M—0 distances in the coordination spheres of the M atoms are bimodal for M = Be or Mg and monomodal for the other alkaline earth metals. Beryllium and magnesium coordination polyhedra containing weak M—0 contacts were classified by variants of their distortions. It is found that the volume of the domains of the Mg, Ca, Sr and Ba atoms is independent of their CNs at CN > 6 (up to 16 for barium). The possibility of using the model of deformable spheres to describe the crystal structure of the compounds investigated is suggested.