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Article 7 of 38

Synthesis and crystal structure of (+)-(2R,3R)-N, N '-bis-trityl-2,3-bis-aziridine
Buijnsters PJJA, van der Reijden FP, Feiters MC, de Gelder R, Sommerdijk NAJM, Nolte RJM, Zwanenburg B
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
29: (2) 179-183 FEB 1999

Document type: Article    Language: English    Cited References: 32    Times Cited: 0   

Abstract:
A new C-2 symmetric bis-aziridine derivative was synthesized starting from L-(+)-tartaric acid. The molecular structure of (+)-(2R, 3R)-N, N'-bis-trityl-2,3-bis-aziridine 4, was determined by H-1, C-13 NMR and elemental analysis and was confirmed by single-crystal X-ray diffraction. Crystal data for 4: C42H36N2, orthorhombic, space group: P2(1)2(1)2(1), a = 12.7633(14), b = 14.5661(6), c = 17.4184(14) Angstrom, and Z = 4.

Author Keywords:
bis-aziridine, C-2-symmetric compound, L-(+)-tartaric acid

KeyWords Plus:
AMIDE-CONTAINING SURFACTANTS, GEMINI SURFACTANTS, CONVENIENT SYNTHESIS, CHIRAL AZIRIDINES, ASSEMBLIES, EXPRESSION, ESTERS

Addresses:
Nolte RJM, Catholic Univ Nijmegen, Dept Organ Chem, NSR Ctr Mol Struct Design & Synth, Toernooiveld 1, NL-6525 ED Nijmegen, Netherlands.
Catholic Univ Nijmegen, Dept Organ Chem, NSR Ctr Mol Struct Design & Synth, NL-6525 ED Nijmegen, Netherlands.
Catholic Univ Nijmegen, Dept Inorgan Chem, NSR Ctr Mol Struct Design & Synth, NL-6525 ED Nijmegen, Netherlands.

Publisher:
KLUWER ACADEMIC/PLENUM PUBL, NEW YORK

IDS Number:
218DR

ISSN:
1074-1542


Article 7 of 38


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