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Molecular structure of (+/-)-5-benzylamino-endo-tricylo[5.2.1.0(2,6)]dec-4-en-3-one
de Gelder R, Smits JMM, Bakkeren FJAD, Klunder AJH
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
27: (11) 677-679 NOV 1997

Document type: Article    Language: English    Cited References: 9    Times Cited: 1   

Abstract:
The crystal and molecular structure of (+/-)-5-benzylamino-endo-tricyclo[5.2.1.0(2,6)]dec-4-en-3-one is described. The X-ray analysis revealed that the reduction of the norbomene double bond is an important process in the irradiation of the used enaminones. The structure was solved by direct methods and refined by least squares methods to R-1 = 0.0468 for 2070 reflections (with I > 2 sigma(I)). Crystal data: C17H19NO, Orthorhombic, space group Pbcn, a = 40.695 (1), b = 6.6928 (1), c = 10.2378(4)Angstrom, V = 2788.44(14)Angstrom(3), Z = 8.

Author Keywords:
crystal structure, tricyclodecadienone, enaminone, photoreduction

Addresses:
de Gelder R, Univ Nijmegen, Nijmegen SON Res Ctr, Dept Inorgan Chem, Toernooiveld 1, NL-6525 ED Nijmegen, Netherlands.
Univ Nijmegen, Nijmegen SON Res Ctr, Dept Inorgan Chem, NL-6525 ED Nijmegen, Netherlands.
Univ Nijmegen, Nijmegen SON Res Ctr, Dept Organ Chem, NL-6525 ED Nijmegen, Netherlands.

Publisher:
PLENUM PUBL CORP, NEW YORK

IDS Number:
YQ504

ISSN:
1074-1542


Article 19 of 38


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